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Preheat oven to 350 degrees F. Coat a 9 x 13-inch baking pan with cooking spray.
Peel and slice peaches to yield 12 cups. Combine peaches, 1 cup sugar and 1/3 cup flour in prepared baking dish and let stand 30 minutes, stirring occasionally.
Combine 1/4 cup sugar, orange rind, orange juice, melted butter, cinnamon and egg whites in a shallow bowl. Trim crust from bread; cut each slice into 2 triangles. Dip each bread slice in egg mixture, coating well. Arrange bread on top of peach mixture. Sprinkle 2 tablespoons sugar over bread. Bake for 45 minutes or until golden brown.
Makes 10 servings.